Synthesis of stable metal-containing porous organic polymers for gas storage

• DOI: 10.1016/j.eurpolymj.2017.03.014
• Publication Date: 2017-03-07T13:03:35Z
• Authors: Gen Li; Qingquan Liu; Bijiang Xia; Jing Huang; Sizhe Li; Yuze Guan; Hu Zhou; Bo Liao; Zhihua Zhou; Bin Liu
• Keywords: Imine

Abstract Stable metal-containing porous organic polymers were prepared by condensation reactions between 1,1′-ferrocenedicarboxaldehyde and meso-diamines to form the imine linkages. Gas adsorption test showed that the obtained polymers exhibited BET surface areas in the range of 715–1050 m 2 g −1 , with CO 2 adsorption capabilities of 14.8% at 273 K/1 bar. This approach represents a new and effective strategy for the preparation of stable metal-containing porous organic polymers.