A preliminary study of some “pseudo-AB2AB2” compounds: RENi4MgRENi4Mg with RE=LaRE=La, Ce and Gd. Structural and hydrogen sorption properties

• DOI: 10.1016/j.ijhydene.2006.11.031
• Publication Date: 2007-01-04T13:26:01Z
• Authors: J BOBET; P LESPORTES; J ROQUEFERE; B CHEVALIER; K ASANO; K SAKAKI; E AKIBA
• Keywords: Hydrogen sorption; Intermetallics; [CHIM.MATE]Chemical Sciences/Material chemistry; 01 natural sciences; Ternary compounds; 0104 chemical sciences

Abstract The compounds RENi 4 Mg have been elaborated by mechanical alloying (MA) and a subsequent heat treatment at 600 ∘ C for 1 h. The lattice parameters are in good agreement with those already reported: 7.165 A ˚ for LaNi 4 Mg , 7.030 A for CeNi 4 Mg and 7.038 A ˚ for GdNi 4 Mg . The hydrogen sorption behaviors are strongly influenced by the rare earth used: for La compound, hydrogen absorption leads to a structural change and no desorption can be observed, for Ce compound, no reaction towards hydrogen can be noticed and for Gd compound, hydrogen can be absorbed and desorbed reversibly at room temperature. Moreover, for GdNi 4 Mg , no structural change is reported after hydrogenation and only a slight volume expansion can be noticed (e.g. 5%). The MA process has also been used successfully for the elaboration of GdNi 4 - x Al x Mg up to x = 1 . In these substituted compounds, hydrogen can also be absorbed and desorbed reversibly at room temperature.