Cobalt and cobalt oxide supported on nitrogen-doped porous carbon as electrode materials for hydrogen evolution reaction

• DOI: 10.1016/j.ijhydene.2018.12.107
• Publication Date: 2019-01-08T20:36:09Z
• Authors: Hongjuan Wang; Ningning Ma; Yonghai Cao; Hao Yu; Jianliang Zuo; Wei Fan; Feng Peng
• Keywords: 02 engineering and technology; 0210 nano-technology; 7. Clean energy

Abstract A facile method is proposed to prepare cobalt supported on nitrogen-doped porous carbon material with high graphitization degree by using chitosan as carbon source, urea as soft template and poloxamer as dispersant. The prepared cobalt-carbon material (Co@NPC) shows that uniformly distributed cobalt nanoparticles are encapsulated in nitrogen-doped porous carbon bundle with large specific surface area. When Co@NPC is applied as electrode in hydrogen evolution reaction, it exhibits superior electrocatalytic performance with low overpotential (η10 = 259 mV), small Tafel slope (99 mV dec−1) and high stability with 83% of its original current density remained after 6 h electrochemical test in 1 M potassium hydroxide electrolyte.