Effect of noble metal addition over active Ru/TiO2 catalyst for CO selective methanation from H2 rich-streams

Technology H2 purification CO selective methanation Energy & Fuels SURFACE 01 natural sciences REMOVAL Noble metals addition Electrochemistry H-2 CHEMISORPTION HYDROGENATION CARBON-MONOXIDE RU CATALYSTS Science & Technology H 2 purification Chemistry, Physical FUEL-CELL SYSTEMS http://vocabularies.unesco.org/thesaurus/concept640 0104 chemical sciences Chemistry GAS Ru-based catalyst Physical Sciences BEHAVIOR
DOI: 10.1016/j.ijhydene.2022.07.072 Publication Date: 2022-08-11T03:12:13Z
ABSTRACT
Selective CO methanation from H2-rich stream has been regarded as a promising route for deep removal of low CO concentration and catalytic hydrogen purification processes. This work is focused on the development of more efficient catalysts applied in practical conditions. For this purpose, we prepared a series of catalysts based on Ru supported over titania and promoted with small amounts of Rh and Pt. Characterization details revealed that Rh and Pt modify the electronic properties of Ru. The results of catalytic activity showed that Pt has a negative effect since it promotes the reverse water gas shift reaction decreasing the selectivity of methanation but Rh increases remarkably the activity and selectivity of CO methanation. The obtained results suggest that RuRh-based catalyst could become important for the treatment of industrial-volume streams.<br/>Junta de Andalucía US-1263288<br/>Ministerio de Ciencia e Innovación RTI2018-096294-B-C3<br/>
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