Evaluation of the inhibition behavior of carbon dots on carbon steel in HCl and NaCl solutions
Carbon steel
Langmuir adsorption model
DOI:
10.1016/j.jmst.2020.01.025
Publication Date:
2020-01-08T21:42:42Z
AUTHORS (7)
ABSTRACT
Abstract An eco-friendly and effective corrosion inhibitor (N-CDs) was acquired by hydrothermal method in methacrylic acid and ethyl(methyl)amine precursors. Afterwards, the weight loss and electrochemistry measurement were chosen to appraise the corrosion inhibition behavior of as-prepared N-CDs for Q235 steel in Cl− contained solutions. The change rules of EIS and Tafel data displayed that the as-prepared N-CDs revealed a high-efficiency protection for steel in all test environments. Meanwhile, the inhibition efficiency of steel reached up to 93.93 % (1 M HCl) and 88.96 % (3.5 wt% NaCl) at 200 mg/L of N-CDs. Furthermore, the N-CDs could form the adsorption film on steel surface to avoid the strong attack of Cl−. By analysis, the adsorption mechanism of as-prepared N-CDs on steel surface was physicochemical interaction, which strictly complied with the Langmuir adsorption model in both solutions.
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