Enhancing corrosion resistance, hardness, and crack resistance in magnetron sputtered high entropy CoCrFeMnNi coatings by adding carbon

• DOI: 10.1016/j.matdes.2021.109711
• Publication Date: 2021-04-09T02:30:58Z
• Authors: León Zendejas Medina; Marcus V. Tavares...; E. Maria Paschalidou; Greta Lindwall; Lars Riekehr; Marcus Korvela; Stefan Fritze; Szilárd Kolozsvári; E. Kristofer Gams...; Leif Nyholm; Ulf Jansson
• Keywords: Oorganisk kemi; Amorphous alloys; Materialkemi; Materials Engineering; 02 engineering and technology; Fragmentation test; Inorganic Chemistry; Corrosion; Materialteknik; Materials Chemistry; TA401-492; Thin film; Bipolar plate; 0210 nano-technology; Materials of engineering and construction. Mechanics of materials; Magnetron sputtering

This study explores carbon addition as a materials design approach for simultaneously improving the hardness, crack resistance, and corrosion resistance of high entropy thin films. CoCrFeMnNi was selected as a starting point, due to its high concentration of weak carbide formers. The suppression of carbides is crucial to the approach, as carbide formation can decrease both ductility and corrosion resistance. Films with 0, 6, and 11 at.% C were deposited by magnetron co-sputtering, using a graphite target and a sintered compound target. The samples with 0 at.% C crystallized with a mixture of a cubic closed packed (ccp) phase and the intermetallic χ-phase. With 6 and 11 at.% C, the films were amorphous and homogenous down to the nm-scale. The hardness of the films increased from 8 GPa in the carbon-free film to 16 GPa in the film with 11 at.% C. Furthermore, the carbon significantly improved the crack resistance as shown in fragmentation tests, where the crack density was strongly reduced. The changes in mechanical properties were primarily attributed to the shift from crystalline to amorphous. Lastly, the carbon improved the corrosion resistance by a progressive lowering of the corrosion current and the passive current with increasing carbon concentration.