Gas solubility, diffusivity and permeability in poly(ethylene oxide)

• DOI: 10.1016/j.memsci.2003.08.031
• Publication Date: 2004-05-08T11:36:16Z
• Authors: H. Lin; B.D. Freeman
• Keywords: 02 engineering and technology; 0210 nano-technology; 01 natural sciences; 7. Clean energy; 0104 chemical sciences

Abstract The effect of pressure on the solubility, diffusivity, and permeability of He, H 2 , O 2 , N 2 , CO 2 , CH 4 , C 2 H 4 , C 2 H 6 , C 3 H 6 and C 3 H 8 in poly(ethylene oxide) (PEO) is reported at 35 °C. Additionally, the temperature dependence of permeability is reported. The effect of polar ether linkages in PEO on gas transport is illustrated by comparing transport properties in PEO with those in polyethylene (PE). For example, at 35 °C and infinite dilution, semi-crystalline PEO exhibits CO 2 permeability coefficient of 12 Barrers, and CO 2 /H 2 and CO 2 /N 2 pure gas selectivities of 6.7 and 48, respectively. In contrast, at similar conditions, the permeability of PE to CO 2 is 13 Barrers, but the CO 2 /N 2 selectivity is only 13. In addition to good separation properties for quadrupolar–nonpolar gas pairs, PEO also shows interestingly high selectivity for olefins over paraffins, which is ascribed to favorable interaction between the polar ether groups in PEO and olefins. For example, the infinite dilution permeability of PEO to propylene is 3.8 Barrers and pure gas propylene–propane selectivity is 2.7 at 35 °C. At similar conditions, PE exhibits propylene–propane selectivity of only 1.4.