Preparation and characterization of a thin-film composite reverse osmosis membrane using a polysulfone membrane including metal-organic frameworks

• DOI: 10.1016/j.memsci.2017.07.034
• Publication Date: 2017-07-17T14:01:48Z
• Authors: Hee Min Park; Ki Yong Jee; Yong Taek Lee
• Keywords: 02 engineering and technology; 0210 nano-technology; 6. Clean water

Abstract The objectives of this paper were to elucidate the performance of a thin-film composite (TFC) reverse osmosis (RO) membrane by modifying the support layer. In order to improve the hydrophilicity and porosity of the support layer, we prepared a polysulfone (PSf) membrane containing an HKUST-1 [Cu 3 (BCT 2 )] metal organic framework (MOF) treated with sulfuric acid for the stability of water. N,N-dimethylformamide (DMF)/water was used as the solvent/non-solvent pair, and the TFC RO membrane was formed by the interfacial polymerization of m-phenylene diamine (MPD) in aqueous solution with trimesoyl chloride (TMC) in organic solution on the MOF/PSF support layer. The optimized concentration of MPD-TMC was investigated through XPS, and the manufactured membrane had a thin, smooth film when paired with a hydrophilic and porous support layer. The active layer thickness of novel membrane was 0.029 µm via FTIR analysis that the thickness compared to a commercial RO membrane having a thickness of 0.2 µm. Also, the novel membrane showed improved flux and fouling resistance compared to the TFC RO membrane with a PSF support layer, without altering the salt rejection property.