Cu(II), Co(II), Fe(III) or VO(II) Schiff base complexes immobilized onto CMK-3 for styrene epoxidation

• DOI: 10.1016/j.micromeso.2015.09.020
• Publication Date: 2015-09-18T18:47:47Z
• Authors: Xiufang Wang; Shujie Wu; Zhifang Li; Xiaoyuan Yang; Hailiang Su; Jing Hu; Qisheng Huo; Jingqi Guan; Qiubin Kan
• Keywords: Styrene oxide; Isobutyraldehyde

Abstract Schiff base complexes containing transition metals (Cu, Co, Fe or V) were successfully immobilized onto amino-functionalized CMK-3 via a stepwise procedure as heterogeneous catalysts for styrene epoxidation. The materials were characterized by means of XRD, N 2 adsorption/desorption, TEM, SEM, FT-IR, Raman, XPS, TG. and ICP-AES. The results of XRD, N 2 adsorption–desorption and TEM revealed that the structure of CMK-3 was well preserved, while the results of FT-IR, TG, Raman, XPS and ICP-AES suggested that the Cu(II), Co(II), Fe(III) or VO(II) Schiff base complexes have been successfully incorporated onto amino-modified CMK-3. Catalytic results showed that high conversion of styrene (94.1%) and selectivity to styrene oxide (73.9%) can be achieved over the heterogeneous Co (II) catalyst with air as the oxidant and isobutyraldehyde as co-reductant. In addition, the functionalized CMK-3 catalyst was quite stable and could be recycled at least three times.