Fabrication of polypropylene/silver nanocomposites for biocidal applications

• DOI: 10.1016/j.msec.2017.02.109
• Publication Date: 2017-02-27T17:01:50Z
• Authors: Washington Luiz O...; Duclerc Fernandes...; Luiz Gustavo Hiro...; Nilton Lincopan; Vijaya Kumar Rangari; Ademar Benevolo L...
• Keywords: Staphylococcus aureus; Silver; Calorimetry, Differential Scanning; Metal Nanoparticles; Polypropylenes; 01 natural sciences; Anti-Bacterial Agents; Nanocomposites; 3. Good health; 0104 chemical sciences; Microscopy, Electron, Transmission; Pseudomonas aeruginosa; Thermogravimetry; Microscopy, Electron, Scanning

This paper presents a study on biocidal effect of polymer nanocomposite films of gamma irradiated polypropylene (PP) and silver nanoparticles. The modified polypropylene was obtained from isotactic polypropylene (iPP) in pellets form by irradiation with gamma rays in the presence of acetylene. A new morphology with long chain branching of PP and distinct rheology is obtained by this process. The blend of 50/50wt% neat PP and PP modified by gamma radiation were further mixed using a twin screw extruder. The AgNPs were infused into this polymer blend at different concentrations of: 0.1%; 0.25%; 0.5%; 1.0%; 1.0% (PVP), 2.0% and 4.0% by wt%. These polymer nanocomposites were characterized by Raman spectroscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), thermogravimetric analysis (TG), differential scanning calorimetry (DSC), X-ray diffraction (XRD), transmission electron microscopy (TEM), cytotoxicity test and Kirby-Bauer disk diffusion techniques. The bactericidal effect of Pseudomonas aeruginosa (P. aeruginosa) and Staphylococcus aureus (S. aureus) were assessed in detail.