Fabrication and release behavior of nitrapyrin Microcapsules: Using modified melamine-formaldehyde resin as shell material

• DOI: 10.1016/j.scitotenv.2019.135394
• Publication Date: 2019-11-21T16:57:08Z
• Authors: Zhang Zhong-qing; Gao Qiang; Yang Jing-min; Wang Yan; Yang Jing-yi; Zhang Xue; Feng Guo-zhong; Cheng Zhi-Qiang; Wang Shao-jie; Su Hong-ge
• Keywords: 02 engineering and technology; 0210 nano-technology; 6. Clean water

As a commonly used nitrification inhibitor, nitrapyrin can significantly improve the utilization of nitrogen in soils. However, the effectiveness of the traditional dosage form of nitrapyrin is reduced by soil adsorption. In this study, nitrapyrin was encapsulated into a melamine-formaldehyde resin microcapsule with good dispersion and release behavior using an in situ polymerization method. The nitrapyrin microcapsules were characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, transmission electron microscopy, and particle-size analysis. The results indicated that the microcapsules had a spherical-shell structure, a uniform morphology with nanoscale micropores on the surface, and a decent nitrapyrin loading content (67.19%). Tests revealed that the release behavior of the nitrapyrin microcapsules was outstanding and conformed to the double-release kinetic model. These results of this study indicate that the nitrapyrin microcapsules can be applied as nitrification inhibitors with beneficial environmental effects and high efficacy.