Synthesis and photoluminescence properties of BF2 complexes with 1,3-diketone ligands

• DOI: 10.1016/j.tet.2007.07.004
• Publication Date: 2007-07-11T11:25:44Z
• Authors: Katsuhiko Ono; Kyohei Yoshikawa; Yujiro Tsuji; Hiroyuki Yamaguchi; Rie Uozumi; Masaaki Tomura; Keijiro Taga; Katsuhiro Saito
• Keywords: 01 natural sciences; 0104 chemical sciences

Abstract BF2 complexes with 1,3-diketone ligands were synthesized, and their optical and electrochemical properties were studied. The colors of the complexes varied depending on the structures of the 1,3-diketone ligands. The absorption and emission maxima of the complexes with 1,3-diaryl-1,3-diketone ligands were considerably red shifted as compared to those of the complexes with 1-aryl-3-trifluoromethyl-1,3-diketone ligands, suggesting an extended π-conjugation of the 1,3-diaryl-1,3-diketone moieties. The molar absorption coefficients and quantum yields of the complexes with 1,3-diaryl-1,3-diketone ligands were larger than those of the complexes with 1-aryl-3-trifluoromethyl-1,3-diketone ligands. Cyclic voltammetry measurements revealed that the reduction potentials of the BF2 complexes were higher than those of the free ligands. These complexes exhibited various emission colors in the solid states due to the intermolecular interactions.