Gd Metal–Organic Framework Thin Film for On-Chip Local Magnetic Refrigeration

• DOI: 10.1021/acs.chemmater.4c00909
• Publication Date: 2024-08-20T06:41:00Z
• Authors: Inés Tejedor; Dmitry E. Kravchenko; Jesús Gandara-Loe; Rob Ameloot; Ignacio Gascón; Olivier Roubeau
• Keywords: Technology; MOLECULAR COOLERS; Science & Technology; Chemistry, Physical; Materials Science; 500; Materials Science, Multidisciplinary; ADIABATIC DEMAGNETIZATION; 530; 01 natural sciences; 0104 chemical sciences; Chemistry; Physical Sciences

Dense metal-organic frameworks with high spin paramagnetic nodes are competitive materials for cryogenic magnetic refrigeration, particularly in applications for which local cooling is advantageous. We focus on obtaining thin films of gadolinium formate, which has a large volumetric magnetocaloric effect. Continuous and homogeneous deposits of gadolinium formate are successfully formed on silicon by means of aerosol jet printing, with control over the film thickness from 0.35 μm up to 2.5 μm. The excellent cooling power of the deposits is evidenced via direct measurements of the cooling of a 200 μm silicon wafer down to sub-K temperatures by a single demagnetization from 1 T and 2 K, thereby demonstrating the potential of this approach for on-chip local magnetic refrigeration.