Synthesis and Properties of 4- and 10-Benzoyl-1-azapyrenes

• DOI: 10.1021/acs.joc.3c01752
• Publication Date: 2024-02-01T02:28:42Z
• Authors: Arpine Vardanyan; Miguel A. Argüell...; Stefan Lochbrunner; Alexander Villinger; Peter Ehlers; Peter Langer

A series of 4- and 10-benzoyl-1-azapyrenes were prepared by a combination of Pd-catalyzed cross-coupling reactions and Brønsted-acid-mediated alkyne-carbonyl-metathesis (ACM). The photophysical and electrochemical properties of the products were studied and compared to theoretical results.