Semipinacol Rearrangement of Iododifluorohomoallyl Alcohols and Its Application in the Allylic C–H Esterification Reactions

Catalytic cycle
DOI: 10.1021/acs.joc.3c02559 Publication Date: 2024-02-12T06:57:02Z
ABSTRACT
We herein present a study on the Ag(I)-mediated semipinacol rearrangement of iododifluorohomoallyl alcohols, resulting allylic difluoromethyl ketones underwent oxidative C-H esterification under palladium catalysis in absence external ligand. This process yielded range derived from allyl esters single operation. The reaction features broad scope
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