Semipinacol Rearrangement of Iododifluorohomoallyl Alcohols and Its Application in the Allylic C–H Esterification Reactions
Catalytic cycle
DOI:
10.1021/acs.joc.3c02559
Publication Date:
2024-02-12T06:57:02Z
AUTHORS (7)
ABSTRACT
We herein present a study on the Ag(I)-mediated semipinacol rearrangement of iododifluorohomoallyl alcohols, resulting allylic difluoromethyl ketones underwent oxidative C-H esterification under palladium catalysis in absence external ligand. This process yielded range derived from allyl esters single operation. The reaction features broad scope
SUPPLEMENTAL MATERIAL
Coming soon ....
REFERENCES (42)
CITATIONS (1)
EXTERNAL LINKS
PlumX Metrics
RECOMMENDATIONS
FAIR ASSESSMENT
Coming soon ....
JUPYTER LAB
Coming soon ....