Photoinduced Catalyst-Free Deuterodefunctionalization of Aryltriazenes with CDCl3

• DOI: 10.1021/acs.orglett.4c01350
• Publication Date: 2024-05-14T16:22:07Z
• Authors: Bin Wang; Yang Shao; Ziren Chen; Yu Xia; Fei Xue; Weiwei Jin; Shaofeng Wu; Yonghong Zhang; Chenjiang Liu

A photoinduced deuterodetriazenation of aryltriazenes with CDCl3 under catalyst-free conditions is reported. The reactions featured simple operation, ecofriendly conditions, readily available reagents, inexpensive D sources, precise site selectivity, and a wide range substrates. Since could be synthesized from arylamine, this protocol can used as general method for easily accurately incorporating deuterium into aromatic systems by using source.