Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether
Sulfonium
Carbenoid
Ylide
Trifluoromethylation
DOI:
10.1021/acs.orglett.5b01170
Publication Date:
2015-05-14T19:35:41Z
AUTHORS (5)
ABSTRACT
A highly efficient Rh-catalyzed carbenoid addition to trifluoromethylthioether for the formation of trifluoromethyl-substituted sulfonium ylide is described. The can act as an electrophilic trifluoromethylation reagent, demonstrated by β-ketoesters and aryl iodides.
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