Syn-Selective Synthesis of β-Branched α-Amino Acids by Alkylation of Glycine-Derived Imines with Secondary Sulfonates

Alkylation Molecular Structure Carboxylic Acids Glycine Esters Stereoisomerism 01 natural sciences Catalysis 3. Good health 0104 chemical sciences 13. Climate action Imines Amino Acids Sulfonic Acids
DOI: 10.1021/acs.orglett.5b02448 Publication Date: 2015-10-07T13:52:28Z
ABSTRACT
AbstractThe utility of the method is demonstrated by the synthesis of the pharmaceutically relevant glutamic acid derivative (VII) as well as the kilogram‐scale preparation of (VIII).
SUPPLEMENTAL MATERIAL
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