Synthesis of the C1–C10 Fragment of Madeirolide A

01 natural sciences 0104 chemical sciences 3. Good health
DOI: 10.1021/acs.orglett.6b00777 Publication Date: 2016-04-14T16:04:44Z
ABSTRACT
The synthesis of a fully elaborated C1-C10 fragment of madeirolide A has been achieved via a strategy based on a series of stereospecific processes. The concise synthetic route also features an iridium-catalyzed visible light induced radical cyclization for construction of the THP ring and a palladium-catalyzed glycosylation for formation of the α-cineruloside linkage.
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