Copper-Catalyzed Stereodefined Construction of Acrylic Acid Derivatives from Terminal Alkynes via CO2 Insertion

01 natural sciences 0104 chemical sciences
DOI: 10.1021/acs.orglett.6b03860 Publication Date: 2017-02-08T21:48:13Z
ABSTRACT
IPrCuCl catalyzes the CO2 insertion reaction undergone by a dialkylvinylborane intermediate derived from alkynyltrialkylborate by a 1,2-alkyl group migration to afford α-alkyl acrylic acids with excellent regio- and stereoselectivities.
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