Adducts of Triallylborane with Ammonia and Aliphatic Amines as Stoichiometric Allylating Agents for Aminoallylation Reaction of Carbonyl Compounds

• DOI: 10.1021/acs.orglett.8b01317
• Publication Date: 2018-06-06T12:23:46Z
• Authors: Nikolai Yu. Kuzne...; Rabdan M. Tikhov; Tatiana V. Strelkova; Yuri N. Bubnov
• Keywords: 01 natural sciences; 0104 chemical sciences

Triallylborane-amines adducts are effective stoichiometric allylating agents in the aminoallylation reaction of carbonyl compounds in methanol. Moreover, copper-catalyzed diastereoselective allylation of Ellman's imine was achieved with triallylborane-methylamine adduct.