Total Synthesis of Applanatumol B
Molecular Structure
Cyclization
Terpenes
Ganoderma
Stereoisomerism
01 natural sciences
0104 chemical sciences
DOI:
10.1021/acs.orglett.9b01901
Publication Date:
2019-07-05T11:55:31Z
AUTHORS (4)
ABSTRACT
The first total synthesis of applanatumol A has been achieved in a highly stereocontrolled manner. The synthetic method includes Fráter-Seebach alkylation, intramolecular aldol reaction, and stereoselective tandem cyclization.
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