Wearable Electronics Based on the Gel Thermogalvanic Electrolyte for Self-Powered Human Health Monitoring

• DOI: 10.1021/acsami.1c12443
• Publication Date: 2021-07-30T17:57:21Z
• Authors: Chenhui Bai; Zhaosu Wang; Shuai Yang; Xiaojing Cui; Xuebiao Li; Yifan Yin; Min Zhang; Tao Wang; Shengbo Sang; Wendong Zhang; Hulin Zhang
• Keywords: Iron; 02 engineering and technology; Body Temperature; 3. Good health; Wearable Electronic Devices; Fluorocarbon Polymers; Polyvinyl Alcohol; Humans; Polyvinyls; Pliability; 0210 nano-technology; Gels; Monitoring, Physiologic

There is always a temperature difference of more than 10 degrees between the human body, as a sustainable heat source, and the ambient temperature. Converting body heat into electricity that in turn is used to drive personal medical electronics is of significance in smart wearable medicine. To avoid the frangibility and complex preparation of traditional thermoelectric materials, we fabricated a gel electrolyte-based thermogalvanic generator with Fe3+/Fe2+ as a redox pair, which presents not only moderate thermoelectric performance but also excellent flexibility. With a micropore-widespread polyvinylidene fluoride diaphragm implanted in the gel, a thermal barrier was created between the two halves, effectively improving the Seebeck coefficient by reducing its thermal conductivity. Considering the superior temperature response of the gel, a self-powered body temperature monitoring system was established by conformally affixing it to the forehead. Meanwhile, the gel patch with a high specific heat capacity can effectively cool down fever patients. This work may offer a new train of thought for exploiting self-powered wearable medical electronics by scavenging low-grade body heat.