Kinetic and Thermodynamic Control of Structure Transformations in a Family of Cobalt(II)–Organic Frameworks

• DOI: 10.1021/acsami.7b12925
• Publication Date: 2017-09-18T13:25:49Z
• Authors: Qiang Chen; Rui Feng; Jian Xu; Yan-Yuan Jia; Ting-Ting Wang; Ze Chang; Xian-He Bu
• Keywords: Kinetic control

Dynamic metal-organic frameworks (MOFs) that respond to external stimuli have recently attracted great attention. However, the subtle control of dynamic processes as well illustration underlying mechanism, which is crucial for targeted construction and modulation purpose, extremely challenging. Herein, we report achievement simultaneous kinetic thermodynamic structure transformation a family cobalt(II)-organic frameworks, through rational combination coligand replacement, solvent molecule substitution, ligand-based solid solution strategies. On basis systematic investigation structural behaviors, response mechanism principles were illustrated. It expected this work can provide valuable hints study further development materials.