Open-Framework Chalcogenide Showing Both Intrinsic Anhydrous and Water-Assisted High Proton Conductivity

• DOI: 10.1021/acsami.7b17189
• Publication Date: 2017-12-29T15:59:21Z
• Authors: Hong-Bin Luo; Mei Wang; Jin Zhang; Zheng-Fang Tian; Yang Zou; Xiao-Ming Ren
• Keywords: 7. Clean energy; 01 natural sciences; 0104 chemical sciences

Proton-conducting materials have attracted increasing interest because of the promising technological applications as key components in various electrochemical devices. It is of great significance for technique application to seek superior proton-conducting materials, operating under both anhydrous and humidified conditions in a wide temperature range. Herein we demonstrate the proton conductance of an open-framework chalcogenide, (CH3NH3)2Ag4Sn3S8 (1), and the postsynthesis product 2 achieved by doping hydrochloric acid into 1. Hybrid 2 displays both intrinsic anhydrous and water-assisted high proton conductance, with σ = 1.87 × 10-4 S·cm-1 at 463 K under N2 atmosphere and 1.14 × 10-3 S·cm-1 at 340 K and 99% relative humidity, and these conductivities are comparable to that in the efficient metal-organic frameworks-based proton-conducting materials. Moreover, hybrid 2 shows excellent thermal stability and long-term stability of proton conduction.