Fabrication of MOF Thin Films at Miscible Liquid–Liquid Interface by Spray Method

• DOI: 10.1021/acsami.8b09812
• Publication Date: 2018-07-27T10:45:27Z
• Authors: Xiao-jue Bai; Dan Chen; Lin-lin Li; Lei Shao; Wen-xiu He; Huan Chen; Yu-nong Li; Xue-min Zhang; Li-ying Zhang; Tie-qiang Wang; Yu Fu; Wei Qi
• Keywords: 01 natural sciences; 0104 chemical sciences

Metal-organic frameworks (MOFs) are an intriguing class of porous crystalline inorganic-organic hybrid materials. The fabrication oriented, thin film MOFs is expected to open novel avenues traditional applications and serve myriad advanced technologies. Here, a facile spray-assisted miscible liquid-liquid interface (MLLI) synthetic strategy carried out reported under mild condition that utilizes for the rapid controllable large-area free-standing MOF films. methodology can employ various metal nodes organic ligands yield high quality lamellar/granulous films at MLLI, which indicates universality MLLI strategy.