Solution Processed CH3NH3PbI3–xClx Perovskite Based Self-Powered Ozone Sensing Element Operated at Room Temperature

• DOI: 10.1021/acssensors.7b00761
• Publication Date: 2017-12-01T11:58:51Z
• Authors: George Kakavelakis; Emmanouil Gagaoud...; Konstantinos Petr...; Valia Petromichelaki; Vassilis Binas; George Kiriakidis; Emmanuel Kymakis
• Keywords: Titanium; Electric Conductivity; Temperature; Reproducibility of Results; Oxides; 02 engineering and technology; Calcium Compounds; Sensitivity and Specificity; 7. Clean energy; 01 natural sciences; 0104 chemical sciences; Ozone; Lead; Semiconductors; Electric Impedance; 0210 nano-technology

Hybrid lead halide spin coated perovskite films have been successfully tested as portable, flexible, operated at room temperature, self-powered, and ultrasensitive ozone sensing elements. The electrical resistance of the hybrid lead mixed halide perovskite (CH3NH3PbI3-xClx) sensing element, was immediately decreased when exposed to an ozone (O3) environment and manage to recover its pristine electrical conductivity values within few seconds after the complete removal of ozone gas. The sensing measurements showed different response times at different gas concentrations, good repeatability, ultrahigh sensitivity and fast recovery time. To the best of our knowledge, this is the first time that a lead halide perovskite semiconductor material is demonstrating its sensing properties in an ozone environment. This work shows the potential of hybrid lead halide based perovskites as reliable sensing elements, serving the objectives of environmental control, with important socioeconomic impact.