Sorption-Enhanced Dry Reforming of Methane in a DBD Plasma Reactor for Single-Stage Carbon Capture and Utilization

• DOI: 10.1021/acssuschemeng.4c02502
• Publication Date: 2024-07-06T13:25:32Z
• Authors: Rani Vertongen; Giulia De Felice; Huub van den Bogaard; Fausto Gallucci; Annemie Bogaerts; Sirui Li
• Keywords: dielectric barrier discharge; sorbent; 01 natural sciences; 0104 chemical sciences; carbon capture and utilization; dry reforming of methane; Chemistry; SDG 7 - Affordable and Clean Energy; zeolite; Engineering sciences. Technology; plasma; SDG 7 – Betaalbare en schone energie

Plasma-sorbent systems are a novel technology for single-stage carbon capture and utilization (CCU), where the plasma enables the desorption of CO2 from a sorbent and the simultaneous conversion to CO. In this study, we test the flexibility of a plasma-sorbent system in a single unit, specifically for sorption-enhanced dry reforming of methane (DRM). The experimental results indicate the selective adsorption of CO2 by the sorbent zeolite 5A in the first step, and CH4 addition during the plasma-based desorption of CO2 enables DRM to various value-added products in the second step, such as H2, CO, hydrocarbons, and the byproduct H2O. Furthermore, our work also demonstrates that zeolite has the potential to increase the conversion of CO2 and CH4, attributed to its capability to capture H2O. Aside from the notable carbon deposition, material analysis shows that the zeolite remains relatively stable under plasma exposure.