Template-Free Synthesis of Monodispersed and Single-Crystalline Cantaloupe-like Fe2O3 Superstructures

• DOI: 10.1021/cg060454t
• Publication Date: 2007-01-10T13:00:52Z
• Authors: Lu-Ping Zhu; Hong-Mei Xiao; Shao-Yun Fu
• Keywords: 02 engineering and technology; 0210 nano-technology

Monodispersed and single-crystalline cantaloupe-like Fe2O3 superstructures have been successfully prepared by a template-free hydrothermal synthetic route. The as-obtained products are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), vibrating sample magnetometer (VSM), and nitrogen adsorption−desorption measurement. The TEM and SEM images show that cantaloupe-like Fe2O3 superstructures composed of well-aligned Fe2O3 nanorods have an average length of 1.5 μm and a mean diameter of 500 nm. The as-prepared Fe2O3 superstructures have a comparatively small Brunauer−Emmett−Teller (BET) surface area of about 9.82 m2/g. Magnetic hysteresis measurements reveal that cantaloupe-like Fe2O3 superstructures display normal ferromagnetic behaviors with the remanence and coercivity of 0.2182 emu/g and 2279.0 Oe at room temperature. The formation mechanism of cantaloupe-like Fe2O3 superstructures is also discussed.