Alkaline Stability of Benzyl Trimethyl Ammonium Functionalized Polyaromatics: A Computational and Experimental Study

• DOI: 10.1021/cm502422h
• Publication Date: 2014-10-01T20:04:57Z
• Authors: Yoong-Kee Choe; Cy Fujimoto; Kwan-Soo Lee; Luke T. Dalton; Kathy Ayers; Neil J. Henson; Yu Seung Kim
• Keywords: 01 natural sciences; 0104 chemical sciences

Alkaline stability of benzyl trimethylammonium (BTMA)-functionalized polyaromatic membranes was investigated by computational modeling and experimental methods. The barrier height of hydroxide initiated aryl-ether cleavage in the polymer backbone was computed to be 85.8 kJ/mol, a value lower than the nucleophilic substitution of the α-carbons on the benzylic position of BTMA cationic functional group, computed to be 90.8 kJ/mol. The barrier heights of aryl–aryl cleavage (polymer backbone) are 223.8–246.0 kJ/mol. The computational modeling study suggests that the facile aryl–ether cleavage is not only due to the electron deficiency of the aryl group but also due to the low bond dissociation energy arising from the ether substituent. Ex situ degradation studies using Fourier transform infrared (FTIR) and 1H nuclear magnetic resonance (NMR) spectroscopy indicated that 61% of the aryl–ether groups degraded after 2 h of treatment in 0.5 M NaOH at 80 °C. BTMA cationic groups degraded slowly over 48 h under the ...