Analysis of the Mo Speciation in the JEB Tailings Management Facility at McClean Lake, Saskatchewan

• DOI: 10.1021/es404980x
• Publication Date: 2014-03-25T20:38:03Z
• Authors: John R. Hayes; Andrew P. Grosvenor; John Rowson; Kebbi Hughes; Ryan A. Frey; Joel Reid
• Keywords: Molybdenum; Principal Component Analysis; Spectrometry, X-Ray Emission; 01 natural sciences; Mining; Saskatchewan; Lakes; X-Ray Absorption Spectroscopy; X-Ray Diffraction; Uranium; Adsorption; Powders; Oxidation-Reduction; Water Pollutants, Chemical; 0105 earth and related environmental sciences

The JEB Tailings Management Facility (TMF) is central to reducing the environmental impact of the uranium ore processing operation located at the McClean Lake facility and operated by AREVA Resources Canada (AREVA). The geochemical controls of this facility are largely designed around the idea that elements of concern, such as Mo, will be controlled in the very long term through equilibrium with supporting minerals. However, these systems are far from equilibrium when the tailings are first placed in the TMF, and it can take years, decades, or centuries to reach equilibrium. Therefore, it is necessary to understand how these reactions evolve toward an equilibrium state to understand the very long-term behavior of the TMF and to ensure that the elements of concern will be adequately contained. To this end, the Mo speciation in a series of samples taken from the JEB TMF during the 2008 sampling campaign has been analyzed. This analysis was performed using powder X-ray diffraction (XRD), X-ray fluorescence mapping (μ-XRF), and X-ray absorption near-edge spectroscopy (XANES). These results show that only XANES was effective in speciating Mo in the tailings samples, because it was both element-specific and sensitive enough to detect the low concentrations of Mo present. These results show that the predominant Mo-bearing phases present in the TMF are powellite, ferrimolybdite, and molybdate adsorbed on ferrihydrite.