Creating New Binding Sites in Ligands and Metal Complexes Using the Negishi Cross-Coupling Reaction

• DOI: 10.1021/ic026043t
• Publication Date: 2003-01-06T06:04:01Z
• Authors: Yuan-Qing Fang; Matthew I. J. Polson; Garry S. Hanan
• Keywords: Negishi coupling; Osmium; Coupling reaction

The Negishi cross-coupling reaction creates a new binding site in ruthenium complex with high efficiency as exemplified by the synthesis of heterodimetallic ruthenium-osmium complex.