Pore Distortion in a Metal–Organic Framework for Regulated Separation of Propane and Propylene
Propane
Propene
Selective adsorption
DOI:
10.1021/jacs.1c10423
Publication Date:
2021-11-15T17:39:30Z
AUTHORS (14)
ABSTRACT
The development of porous solids for adsorptive separation propylene and propane remains an important challenging line research. State-of-the-art sorbent materials often suffer from the trade-off between adsorption capacity selectivity. Here, we report regulated in a metal-organic framework via designed pore distortion. distorted structure HIAM-301 successfully excludes thus achieved simultaneously high selectivity (>150) large (∼3.2 mmol/g) at 298 K 1 bar. Dynamic breakthrough measurements validated excellent propylene. In situ neutron powder diffraction inelastic scattering revealed binding domains adsorbed molecules as well host-guest interaction dynamics. This study presents new benchmark propane.
SUPPLEMENTAL MATERIAL
Coming soon ....
REFERENCES (26)
CITATIONS (110)
EXTERNAL LINKS
PlumX Metrics
RECOMMENDATIONS
FAIR ASSESSMENT
Coming soon ....
JUPYTER LAB
Coming soon ....