Direct Detection of the α-Carbon Radical Intermediate Formed by OspD: Mechanistic Insights into Radical S-Adenosyl-l-methionine Peptide Epimerization

• DOI: 10.1021/jacs.3c13829
• Publication Date: 2024-02-16T23:37:55Z
• Authors: William G. Walls; Anna L. Vagstad; Tyler Delridge; Jörn Piel; William E. Broderick; Joan B. Broderick
• Keywords: Isotopic labeling; Hydrogen atom abstraction; Epimer

OspD is a radical