A Multimetal Approach for the Reticulation of Iridium into Metal–Organic Framework Building Units

• DOI: 10.1021/jacs.4c08638
• Publication Date: 2024-09-04T04:42:32Z
• Authors: Raluca Loredana V...; M. Carmen Borrall...; Fátima Esteban-Be...; Alina A. Skorynina; Miguel Gomez-Mendoza; Victor A. de la P...; Enrique Gutiérrez...; Marta Iglesias; M. Ángeles Monge; Felipe Gándara

Noble metal elements are ubiquitous in our everyday life, from medical applications to electronic devices and synthetic chemistry. Iridium is one of the least abundant elements, and despite its scarcity, it remains essential for efficient and active catalytic processes. Consequently, the development of heterogeneous catalysts with the presence of active iridium sites is of enormous interest as it leads to the improvement of their recyclability and reusability. Here, we demonstrate a strategy to incorporate iridium atoms into metal-organic frameworks (MOFs), as part of their secondary building units (SBUs), resulting in robust and reusable materials with heterogeneous photocatalytic activity.