Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C–N, C–C, C–O, C–S, and C–P Bond-Forming Reactions
ARYL HALIDES
TECNOLOGIA DE ALIMENTOS
DIAMINE LIGANDS
ULLMANN
01 natural sciences
MECHANISMS
3. Good health
0104 chemical sciences
QUIMICA ORGANICA
HETEROGENEOUS CATALYSIS
Oxidation
CROSS-COUPLING REACTIONS
GOLD CLUSTERS
TEMPERATURE
COPPER CLUSTERS
DOI:
10.1021/jacs.5b00222
Publication Date:
2015-03-08T18:37:11Z
AUTHORS (10)
ABSTRACT
Sub-nanometric Cu clusters formed by endogenous reduction of salts and nanoparticles are active selective catalysts for C–N, C–C, C–O, C–S, C–P bond-forming reactions. have also been generated within a polymeric film stored with full stability months. In this way, they ready to be used on demand maintain high activity (TONs up 104) selectivity the above A potential mechanism formation sub-nanometric their electronic nature is presented.
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