Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C–N, C–C, C–O, C–S, and C–P Bond-Forming Reactions

ARYL HALIDES TECNOLOGIA DE ALIMENTOS DIAMINE LIGANDS ULLMANN 01 natural sciences MECHANISMS 3. Good health 0104 chemical sciences QUIMICA ORGANICA HETEROGENEOUS CATALYSIS Oxidation CROSS-COUPLING REACTIONS GOLD CLUSTERS TEMPERATURE COPPER CLUSTERS
DOI: 10.1021/jacs.5b00222 Publication Date: 2015-03-08T18:37:11Z
ABSTRACT
Sub-nanometric Cu clusters formed by endogenous reduction of salts and nanoparticles are active selective catalysts for C–N, C–C, C–O, C–S, C–P bond-forming reactions. have also been generated within a polymeric film stored with full stability months. In this way, they ready to be used on demand maintain high activity (TONs up 104) selectivity the above A potential mechanism formation sub-nanometric their electronic nature is presented.
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