Influence of Additives Including Amine and Hydroxyl Groups on Aqueous Ammonia Absorbent for CO2 Capture

• DOI: 10.1021/jp711113q
• Publication Date: 2008-03-19T09:00:33Z
• Authors: Jong Kyun You; HoSeok Park; Seong Ho Yang; Won Hi Hong; Weonho Shin; Jeung Ku Kang; Kwang Bok Yi; Jong-Nam Kim
• Keywords: STOPPED-FLOW TECHNIQUE; CARBON-DIOXIDE; GREENHOUSE-GAS; KINETICS; REMOVAL; ALKANOLAMINES; SOLVENTS; SINGLE; 02 engineering and technology; 0210 nano-technology

Aqueous ammonia absorbent (10 wt %) was modified with four kinds of additives (1 wt %) including amine and hydroxyl groups, i.e., 2-amino-2-methyl-1-propanol (AMP), 2-amino-2-methyl-1,3-propandiol (AMPD), 2-amino-2-ethyl-1,3-propandiol (AEPD), and tri(hydroxymethyl) aminomethane (THAM), for CO(2) capture. The loss of ammonia by vaporization was reduced by additives, whereas the removal efficiency of CO(2) was slightly improved. These results were attributed to the interactions between ammonia and additives or absorbents and CO(2) via hydrogen bonding, as verified by FT-IR spectra and computational calculation. Molecular structures as well as binding energies were obtained from the geometries of (ammonia + additives) and (ammonia + additives + CO(2)) at the optimized state. These experimental and theoretical findings demonstrate that additives including amine and hydroxyl group are suitable for modifying aqueous ammonia absorbent for CO(2) removal.