Mechanocatalytic Polymerization and Cross-Linking in a Polymeric Matrix

01 natural sciences 0104 chemical sciences
DOI: 10.1021/mz400201c Publication Date: 2013-06-24T15:03:04Z
ABSTRACT
A latent olefin metathesis catalyst, bearing two polymeric NHC ligands, was embedded in a semicrystalline polymer matrix containing cyclic olefins. The catalyst was activated by straining the solid material under compression, resulting in polymerization and cross-linking reactions of the monomers in situ. Catalyst activation in the solid state may be employed in new self-healing materials.
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