Liquid-Crystalline [60]Fullerene-TTF Dyads

• DOI: 10.1021/ol047829t
• Publication Date: 2005-01-27T05:53:29Z
• Authors: Emmanuel Allard; Frédéric Oswald; Bertrand Donnio; Daniel Guillon; Juan Luis Delgado; Fernando Langa; Robert Deschenaux
• Keywords: Malonate; Derivative (finance); Mesogen

[60]Fullerene was functionalized with a TTF derivative and bis-mesogenic fragment. The synthetic methodology based on the addition of malonate to C60 (Bingel-type reaction). Both dyad showed smectic B A phases. supramolecular organization within layers monolayer type for bilayer fullerene derivative. In latter case, governed by unit.