Syntheses, Structure, and Molecular Cubic Hyperpolarizabilities of Systematically Varied Ethynylgold(I) Complexes

• DOI: 10.1021/om000093t
• Publication Date: 2002-07-26T06:06:21Z
• Authors: José Vicente; María Teresa Chicote; María Dolores Abr...; M. Carmen Ramírez...; Peter G. Jones; Mark G. Humphrey; Marie P. Cifuentes; Marek Samoc; Barry Luther-Davies
• Keywords: 540; 01 natural sciences; 0104 chemical sciences

The reactions of Q[Au(acac)2] (Q = N(PPh3)2 (PPN; a), NPr4 (b); acac = acetylacetonato) with terminal alkynes of the type HC⋮CC6H4R-4 in a 1:2 molar ratio affords the complexes Q[Au(C⋮CC6H4R-4)2] (...