Experimental evidence for superionic water ice using shock compression

• DOI: 10.1038/s41567-017-0017-4
• Publication Date: 2018-02-02T16:46:40Z
• Authors: Marius Millot; Sebastien Hamel; J. Ryan Rygg; Peter M. Celliers; Gilbert W. Collins; Federica Coppari; Dayne E. Fratanduono; Raymond Jeanloz; Damian C. Swift; Jon H. Eggert
• Keywords: 13. Climate action; 0103 physical sciences; 01 natural sciences; 7. Clean energy

In stark contrast to common ice, Ih, water ice at planetary interior conditions has been predicted to become superionic with fast-diffusing (that is, liquid-like) hydrogen ions moving within a solid lattice of oxygen. Likely to constitute a large fraction of icy giant planets, this extraordinary phase has not been observed in the laboratory. Here, we report laser-driven shock-compression experiments on water ice VII. Using time-resolved optical pyrometry and laser velocimetry measurements as well as supporting density functional theory–molecular dynamics (DFT-MD) simulations, we document the shock equation of state of H2O to unprecedented extreme conditions and unravel thermodynamic signatures showing that ice melts near 5,000 K at 190 GPa. Optical reflectivity and absorption measurements also demonstrate the low electronic conductivity of ice, which, combined with previous measurements of the total electrical conductivity under reverberating shock compression, provides experimental evidence for superionic conduction in water ice at planetary interior conditions, verifying a 30-year-old prediction.