Tuning the size and color of the p-type wide band gap delafossite semiconductor CuGaO2 with ethylene glycol assisted hydrothermal synthesis

• DOI: 10.1039/b810064k
• Publication Date: 2008-10-24T10:30:14Z
• Authors: Radhakrishnan Sri...; Benoit Chavillon; Charlotte Doussie...; Laurent Cario; Michael Paris; Eric Gautron; Philippe Deniard; Fabrice Odobel; Stéphane Jobic
• Keywords: [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]; 02 engineering and technology; 0210 nano-technology; [PHYS.COND.CM-MS] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]

Delafossite CuGaO2 is a prototype p-type transparent semiconducting oxide. We report here a new ethylene glycol (EG) mediated hydrothermal synthesis route to this material from soluble hydrated metal nitrates. We found that EG acts as a reducing agent which eases the formation of CuGaO2 by stabilizing Cu(I) at low temperature in hydrothermal conditions. Moreover, we observed that the initial pH of the precursors solution is a key parameter to tune the particle sizes (from 2 µm to 300 nm) and subsequently the color (from dark brown to light gray) of the CuGaO2 powder. The optimal synthesis conditions to obtain the brightest product are described. In these conditions, the CuGaO2 powder exhibits a pale grayish color and contains 300 nm large nano-layered particles approximately 20 nm thick.