A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties

• DOI: 10.1039/c2cc33350c
• Publication Date: 2012-07-26T15:50:54Z
• Authors: José Martínez-Lillo; Laura Cañadillas-...; Joan Cano; Francesc Lloret; Miguel Julve; Juan Faus
• Keywords: 01 natural sciences; 0104 chemical sciences

The compound (NBu(4))(5)[Gd(III){Re(IV)Br(4)(μ-ox)}(4)(H(2)O)]·H(2)O (1), with intramolecular antiferromagnetic coupling, is the first Re(iv) system incorporating a 4f ion.