A general method for the synthesis of polymeric binary flurides exemplified by AgF3, NiF4, RuF4, and OsF4

• DOI: 10.1039/c39890000346
• Publication Date: 2004-03-30T16:15:26Z
• Authors: Boris Zemva; Karel Lutar; Adolf Jesih; William J. Casteel; Neil Bartlett
• Keywords: Anhydrous; Hydrogen fluoride; Oxidation state

Fluride-ion capture from their anion relatives in anhydrous hydrogen fluoride solution by strong ion acceptors such as AsF5 provides a general approach to the synthesis of polymeric binary fluorides and is particularly advantageous highest-oxidation-state transition metal fluorides.