Aggregation-induced emission enhancement of a meso-trifluoromethyl BODIPY via J-aggregation

• DOI: 10.1039/c3sc52495g
• Publication Date: 2013-10-25T13:50:49Z
• Authors: Sohee Choi; Jean Bouffard; Youngmi Kim
• Keywords: 01 natural sciences; 0104 chemical sciences

A CF3-BODIPY forms strongly luminescent aggregates, which contrasts with the quenched condensed-phase photophysics that are typical for BODIPY dyes. Examination of the luminescent properties of these aggregates – narrow red-shifted absorption and emission bands, minimal Stokes shift and increased fluorescence rate constants – and of the solid-state packing of the dye establish the CF3-BODIPY as the first structurally characterized genuine BODIPY J-aggregate.