A kinetic study of the CH2OO Criegee intermediate self-reaction, reaction with SO2and unimolecular reaction using cavity ring-down spectroscopy

• DOI: 10.1039/c4cp04198d
• Publication Date: 2014-12-22T16:02:26Z
• Authors: Rabi Chhantyal-Pun; Anthony Davey; Dudley E. Shallcross; Carl J. Percival; Andrew J. Orr-Ewing
• Keywords: 13. Climate action; 0103 physical sciences; 540; 01 natural sciences; 0104 chemical sciences; 3. Good health

A rate coefficient is reported for the CH2OO self-reaction and evidence presented for SO2-catalysed CH2OO isomerization or intersystem crossing.