Intriguing differences in hydrogen adsorption in CPO-27 materials induced by metal substitution

• DOI: 10.1039/c4ta05794e
• Publication Date: 2014-12-24T13:30:46Z
• Authors: Mali H. Rosnes; Martin Opitz; Matthias Frontzek; Wiebke Lohstroh; Jan Peter Embs; Peter A. Georgiev; Pascal D. C. Dietzel
• Keywords: 01 natural sciences; 0104 chemical sciences

We present a comparative study of hydrogen gas adsorption experiments on CPO-27–Cu and –Mn. The initial isosteric heat of adsorption in CPO-27–Cu is low for a material containing open metal sites and in contrast to the other members of the CPO-27 series, including the Mn compound.