Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes
QD
01 natural sciences
0104 chemical sciences
DOI:
10.1039/c5cc00529a
Publication Date:
2015-02-13T14:30:29Z
AUTHORS (3)
ABSTRACT
Interaction of the reactive 14 VE {Ir(IBioxMe4)3}(+) fragment with fluoroarenes results exclusively in ortho-C-H bond oxidative addition and formation 16 Ir(iii) derivatives [Ir(IBioxMe4)3(Ar)H](+) (Ar = 2-C6H4F, 2,3-C6H3F2, 2,4,6-C6H2F3). The C-H activation reactions occur under mild conditions are reversible.
SUPPLEMENTAL MATERIAL
Coming soon ....
REFERENCES (37)
CITATIONS (12)
EXTERNAL LINKS
PlumX Metrics
RECOMMENDATIONS
FAIR ASSESSMENT
Coming soon ....
JUPYTER LAB
Coming soon ....