Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes

QD 01 natural sciences 0104 chemical sciences
DOI: 10.1039/c5cc00529a Publication Date: 2015-02-13T14:30:29Z
ABSTRACT
Interaction of the reactive 14 VE {Ir(IBioxMe4)3}(+) fragment with fluoroarenes results exclusively in ortho-C-H bond oxidative addition and formation 16 Ir(iii) derivatives [Ir(IBioxMe4)3(Ar)H](+) (Ar = 2-C6H4F, 2,3-C6H3F2, 2,4,6-C6H2F3). The C-H activation reactions occur under mild conditions are reversible.
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