Direct gem-difluoromethylenation of sp3-hybridized carbon center through copper-mediated radical/radical cross-coupling for the construction of a CH2–CF2 linkage

Carbon fibers Center (category theory) Linkage (software)
DOI: 10.1039/c5cc05677b Publication Date: 2015-08-27T10:30:40Z
ABSTRACT
An efficient <italic>gem</italic>-difluoromethylenation of benzyl bromides through copper-mediated direct radical/radical C–C cross-coupling has been developed for the construction CH<sub>2</sub>–CF<sub>2</sub> linkage.
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