Direct evidence of Fe(v) and Fe(iv) intermediates during reduction of Fe(vi) to Fe(iii): a nuclear forward scattering of synchrotron radiation approach

• DOI: 10.1039/c5cp03784k
• Publication Date: 2015-07-30T08:02:20Z
• Authors: Libor Machala; Vít Procházka; Marcel Miglierini; Virender K. Sharma; Zdeněk Marušák; Hans-Christian Wille; Radek Zbořil
• Keywords: Electron Transport; info:eu-repo/classification/ddc/540; 13. Climate action; Iron; Quantum Theory; Scattering, Radiation; 01 natural sciences; Synchrotrons; 0104 chemical sciences

Identification of unstable high-valent iron species in decomposition ferrate(<sc>vi</sc>) advances the understanding mechanisms by ferrates.